I think that although technology with papers and chemicals has moved forward
"Moved" yes; "changed" certainly. But better? That's not so clear cut. When I first started in photography, I almost invariably overexposed by a considerable margin. I didn't have a meter, and nor did I have exposure tables. I never noticed any instructions with the film, but did have a fixed idea in my mind that photographs were only really possible in bright sun, so when the sun wasn't bright - well, I overexposed. This meant that I early on developed an interest in chemical reducers and to a lesser extent, intensifiers to recover the negative. One intensifier used uranium. With later reading in my older years, I found that different intensifiers and reducers did give different results, and uranium (like all of them, really) couldn't be exactly mimicked by anything else. These days, you can't buy uranium intensifer as far as I know. And therefore any unique characteristics it offered can't be reproduced.
Similarly, earlier printing papers (meaning, still within my lifetime and memory) contained heavy metals such as cadmium. Like uranium, they are now banned. I know that some old hands felt that the newer materials were inferior. Obviously, "inferior" depends on what you're comparing it with. Newer materials are better on health and safety grounds, but do they produce better results?
Anecdotal evidence suggests that when the older types of optical glass were banned for containing heavy metals, until newer optical designs could be computed using alternative glasses (that were less than ideal, or they would have been used before the ban) new lenses actually performed worse than older ones. I suspect that given that in 35mm/digital cameras most work has gone into zooms and moving elements to reduce the effort of autofocus, older prime lenses in this size may still outperform most new primes. But this gets us away from large format...
Summing up - not all change is good. Modern limitations on which materials can be used may well mean that inferior results are inevitable.