Do I have this wrong somewhere...
Isn't calculating an EI based on a particular type of film / developer and your own situation (water temp, developing methods etc)
I don't mean to disagree with Martin, but EI has little to do with development as long as you're development time is something in the normal range. You do have to choose a film, but your personal EI is directly related to your meter (not all read the same or are even set to give the same middle gray value; for example, some meters read Zone V at about 18% reflectance, while others are set to 36% reflectance), camera flare, lens flare, shutter and aperture inconsistencies, and probably a couple other things I'm forgetting.
Where development plays into EI is when doing N- development. Generally, EI drops as development is reduced. Therefore, ardent Zone practitioners have tested for all these parameters and will adjust EI on-the-fly if reduced development is anticipated.
Personally, I wouldn't attempt EI testing using any scanner; just a whole gamut of other variables involved. If you want to take an empirical approach, I'd suggest the following:
1. Set your lens focus to infinity and place a black card (I use mount board) in an even, consistent light source. I place mine on the shady side of the house on a clear blue sky (no cloud) day. The message here is that you don't want the light changing on you as you expose film.
2. Set your meter, ISO dial, or whatever to the manufacturer's speed rating, then take a meter reading of the black card (make sure you're in line with the lens and at camera position, if using a spot meter; otherwise, you'll have to move the camera close enough to fill the frame with the black card.
3. Based on the meter reading from #2 (this will be Zone V), reduce exposure by 4 stops, thereby exposing for Zone I. I would strongly recommend setting shutter speed on one value and varying aperture for the remaining exposures. You'll be opening/closing the aperture a stop or two over/under so make sure you have the aperture range to complete the test. For example, if you had a 2.8 lens on the camera you wouldn't start at f/4.
4. Make exposure at meter reading, then make additional exposures opening/closing the aperture 1/2 stop until all exposures cover a range of 1 stop over (in general, film is rarely faster than the manufacturer states) to 2 stops under.
5. Develop the film using your chosen developer and normal development time; stop, fix, wash, etc, as normal.
6. When the film is dry, you're looking for that exposure that provides a very slight amount of density when compared to the unexposed film edge. This is much easier to see with LF film vs 35mm. If you want, I think I have a sheet of film showing what I'm talking about and I can try to take a picture of it with my phone and post here.
Doing this little bit of testing will get you pretty darn close...close enough that you could adjust your EI as experience dictates.